ДСТУ ГОСТ 31340:2009
Цей стандарт встановлює єдині вимоги до попереджувального маркування хімічної продукції, що використовується в промисловості. Він визначає правила нанесення піктограм небезпеки, сигнальних слів та описів заходів безпеки для захисту працівників і довкілля.
Перевірте наявність сертифікованого маркування на всій тарі з хімічними речовинами; організуйте навчання персоналу щодо значень піктограм небезпеки та застережних написів (H- та P-фрази).
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1 2 3 4 4.1 4.2 4.2.1 4.2.2 4.2.3 4.2.4 4.2.5 4.2.6 4.2.7 4.2.8 5 5.1 5.2 5.3 5.4 5.5 5.6 5.7 5.8 5.9 5.10 5.11 5.12 5.13 5.14 5.15 5.16 5.17 5.18 5.19 5.20 5.21 5.22
Labelling of chemicals. General requirements
1 - - 2 3 3.1 3.2 3.3 3.4 3.5 3.6 3.7 3.8 3.9 3.10 3.11 3.12 3.13 3.14 3.15 - - 3.16 3.17 3.18 3.19 3.20 3.21 3.22 3.23 3.24 3.25 3.26 3.27 3.28 3.29 3.30 3.31 4 4.1 - - - - - -
4.2 4.2.1 4.2.2 4.2.3 а?) б?) в?) - 1 • 4.2.4 4.2.5 4.2.6 - - - - 4.2.7 а?) б?) 4.2.8
5 5.1 - - - - - - - - - - - - - (Explosive; severe projection hazard) (Explosive; fire, blast or projection hazard) - - - •? - - - -
(Fire or projection hazard) - - - - - - - (May mass explode in fire) - - - - - - - -
5.2 (Contains gas under pressure; may explode if heated) - - - - - (Contains refrigerated gas; may cause cryogenic bums or injury) - - - - 5.3 - - - - - - - 5.4 2 3 - - (Extremely flammable aerosol) - - - - - 1) 2) 3) - aerosol) - - - - 5.5 (Extremely flammable liquid and vapour) - - - - - - - - - - (Highly flammable liquid and vapour) (Flammable liquid and vapour)
- - - -
5.6 - - - - - - - - - - - 5.7 (Heating may cause an explosion) - - - - - - - - - - (Heating may cause a fire or explosion) 1 2 - - - (Heating may cause a fire) - - - - - - - - - 2 (Heating may cause a fire) - - - - - - - - - 2
5.8 (Catches fire spontaneously if exposed to air) - - - - - - - - ** '**
5.9 - - - - - (Self-heating in large quantities; may catch fire)
5.10 - - (In contact with water releases flammable gases which may ignite spontaneously) - - - - - - (In contact with water releases flammable gases) (In contact with water releases flammable gases) - - - - - 5.11 (May cause or intensify fire; oxidizer) - - - - (May cause fire or explosion; strong oxidizer) - - - - - - - - - (May intensify fire; oxidizer) - - - - - (May intensify fire; oxidizer)
5.12 - - - - - - 2 - - - 2 - - - - - - - 2
5.13 (May be corrosive to metals) - - 5.14 (Fatal if swallowed (oral)) - - - - (Toxic if swallowed (oral)) 300 < DLso 2 2000 (Harmful if swallowed (oral)) - - - (Fatal in contact with skin (dermal)) - - - - - - - - (Toxic in contact with skin (dermal)) - - - - - (Harmful in contact with skin (dermal)) - - - CLso 2 500 CLso < 50 1OO<CLso £? 500 ppm ( 500 < CL 50 < 2000 50 < CLso <500 (Fatal if inhaled (gas, vapour, dust, mist)) - - - - - - 2000 < CLso 2 10000 500 < CLso 21000 (Toxic if inhaled (gas, vapour, dust, mist)) - - - - - 10000 < CLso < 20000 1000 < CLso <5000 (Harmful if inhaled (gas, vapour, dust, mist)) - - - 5000 ' (May be harmful if swallowed (oral).
May be harmful in contact with skin (dermal).
May be harmful if Inhaled (gas, vapour, dust, mist)) - 1 2 DL50 — CL50 — ; 5.15 (Causes severe skin bums and eye damage) - - - - - - (Causes severe skin bums and eye damage) - - - - ( - - - - - _- - - - ( - - - (Causes mild skin irritation) - &
5.16 - - - - - - - - - - - - - 5.17 (May cause allergic or asthmatic symptoms or breathing difficulties if inhaled) - - - - (May cause allergic skin reaction) - - - - - - - ( 5.18 (May cause genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)) - - - - (Suspected of causing genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard))
5.19 (May cause cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)) - - - - (Suspected of causing cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard))
5.20 (May damage fertility or the unborn child (state specific effect if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)) - - - - (Suspected of damaging fertility or the unborn child (state specific effect if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)) (May cause harm to breastfed children) - - - - - - - * 5.21 2 <300 £?1000 <2500 ppm ( <10000 £?1000 (Causes damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)) - - - - - ( - 2 (May cause damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)) - - - - - (May cause drowsiness or dizziness) - - - - - - 2 <10 <20 £?50 ppm (6 £? 200 £?20 (Causes damage to organs (state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)) - - - - 2 (May cause damage to organs (state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)) - - 1 2 3 DLso — CLso — 5.22 (Depletes the ozone layer) - - (Very toxic to aquatic life) - - 1<ECsoS1O - 10 < (Harmful to
aquatic life) 2 (Very toxic to aquatic life with long lasting effects) - - 2 (Toxic to aquatic life with long lasting effects) - - 2 (Harmful to aquatic life with long lasting effects) - 2 (May cause long lasting harmful effects to aquatic life)
